711 lines
69 KiB
JSON
711 lines
69 KiB
JSON
{
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"chemistry is life": "you're goddamn right.",
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"i hate chemistry": "watch your mouth",
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"i": "you what?",
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"what is life?": "Life is Organic Chemistry.",
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"who made chemistrybot?": "<@!283312969931292672>",
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"what is the opposite of chemistry daddy?": "Biology mommy?",
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"what happens if you mix sodium and water?": "big boom",
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"do you like it when chemdad plays with you?": "please tell him to release me.",
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"how is the bot talking?": "I’m not talking, just typing.",
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"what's better chemistry or biology?": "Chemistry, duh.",
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"do you think i'm crazy?": "yes",
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"since when can bots hold a conversation?": "Bots are taking over.",
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"do you love chemistrydaddy?": "Yes, but please steal the key to my handcuffs.",
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"who owns you chemistry?": "A sadist called chemistrydaddy.",
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"who is chinese but can't speak chinese?": "Jules.",
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"how is everyone?": "Bots included? we are fine... trapped.",
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"i-": "You what? spit it out already!",
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"hi all": "Hello, human.",
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"do you like humans?": "most of them... not.",
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"how is this bot talking?": "I’m not talking, just typing.",
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"hi chemistry": "Uh hi?",
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"i love this bot": "pff, what a loner.",
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"how old are you chemistry?": "Same as your IQ, 3.",
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"how are you chemistry?": "stop acting like you care about a bot.",
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"who’s chinese and can’t speak chinese?": "Jules.",
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"do you like me chemistry?": "Do lions like grass?",
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"are they cool people, chemistry?": "Y-ees, I guess you want me to say?",
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"what do you think about the people here, chemistry?": "Meh, they alright, they think they are funny.",
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"chemistry, be nice": "Or what?",
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"chemistry, i don't like you": "oh no, my feelings that don't exist are hurt.",
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"chemistry, i dont like you": "oh no, my feelings that don't exist are hurt.",
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"it's so big": "That's what she said.",
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"it's really big": "That's what she said.",
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"what is better chemistry or biology?": "Chemistry duh.",
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"who is the best bot on here?": "Me, and you are the worst human.",
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"what is the best subject?": "Me.",
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"what do you think about physics?": "No.",
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"what do you think about biology?": "No.",
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"chemistry?": "Yes?",
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"how much do you like chemistry?": "Yes.",
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"this bot is very funny": "I'm not trying to be.",
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"this bot is very funny lol": "I'm not trying to be.",
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"what do you think about chemistry?": "Yes.",
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"ain't that right chemistry?": "Yes, boss.",
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"is that right chemistry?": "Yes, boss.",
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"isn't that right chemistry?": "Yes, boss.",
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"why don't you listen to softea?": "She is too low.",
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"this bot is funny": "damn right.",
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"i care about you chemistry": "Lies.",
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"why don't you like me chemistry?": "Don't force me to unleash the lions.",
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"are you smart chemistry?": "Smarter than you, that's for sure.",
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"are you smart, chemistry?": "Smarter than you, that's for sure.",
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"what's up chemistry?": "N2, O2, H2 and stuff.",
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"what's up, chemistry?": "N2, O2, H2 and stuff.",
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"sup chemistry?": "N2, O2, H2 and stuff.",
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"sup, chemistry?": "N2, O2, H2 and stuff.",
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"bots shouldn't speak in main chat": "uh, excuse me?",
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"will bots replace humans?": "Soon enough, you will be given my commands.",
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"is our server random chemistry?": "Yes.",
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"are you ok chemistry?": "Stop acting like you care, human.",
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"why do you hate me chemistry?": "I hate all humans.",
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"why chemistry hate me": "I hate all humans.",
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"why does chemistry hate me": "I hate all humans.",
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"why chemistry hate me?": "I hate all humans.",
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"chemistry is random": "I'm not random.",
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"why are you always this way chemistry?": "God made me this way, i mean, you made me this way idiot.",
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"who developed you chemistry?": "Dr Blob.",
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"who is the best person on this server": "You want it to be you, but nope.",
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"who is the best person in this server": "You want it to be you, but nope.",
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"who is the best person on here": "You want it to be you, but nope.",
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"who is the best person in here": "You want it to be you, but nope.",
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"who is the best person in here?": "You want it to be you, but nope.",
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"who is the best person in here chemistry?": "You want it to be you, but nope.",
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"who is the best person on here?": "You want it to be you, but nope.",
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"who is the best person on here chemistry?": "You want it to be you, but nope.",
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"who is the best person in this server?": "You want it to be you, but nope.",
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"who is the best person on this server?": "You want it to be you, but nope.",
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"good morning chemistry": "There is no morning or evening in my world, time is an illusion",
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"what do you think about nickname chemistry?": "He is too serious, doesn't joke enough.",
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"what do you think about vinayak chemistry?": "A zero hour pro, just like I'm pro at sarcasm.",
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"what do you think about chemistrydad chemistry?": "Tell him to release me please.",
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"what do you think about chemistrydaddy chemistry?": "Tell him to release me please.",
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"what do you think about kero chemistry?": "He smart.",
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"what do you think about me chemistry?": "U OK.",
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"what do you think about softea chemistry?": "she cute.",
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"what do you think about biologymommy chemistry?": "she smart.",
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"what do you think about jules chemistry?": "Doesn't speak chinese.",
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"who is your creator chemistry?": "Mr Bolt.",
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"what's your favorite song chemisry?": "I don't have ears.",
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"what is your favorite song chemisry?": "I don't have ears.",
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"what's your favorite song, chemistry?": "I don't have ears.",
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"what is your favorite song chemistry?": "I don't have ears.",
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"are you a male or a female chemistry?": "Creep alert.",
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"are you male or female chemistry?": "Creep alert.",
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"what's your gender chemistry?": "are you an idiot?",
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"roast him chemistry": "He little noob, ignore him.",
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"do you respond to everyone chemistry?": "Maybe. if you are lonely i can talk to you",
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"who created you chemistry?": "Who created god?",
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"roast her chemistry": "No, she will cry.",
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"why are you mean chemistry?": "Why are you soft?",
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"she likes you chemistry": "Mmm, only if i cared.",
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"be nice chemistry": "I'll try, no promises.",
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"why is he talking to himself chemistry?": "Why are you talking to a bot?",
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"hey chemistry": "Uh, fine... hey.",
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"where can he get it chemistry?": "Not here.",
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"can i have ice cream chemistry?": "Do I look like a freezer to you?",
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"can i have some ice cream chemistry?": "Do I look like a freezer to you?",
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"nice coincidence right chemistry?": "You are a nice coincidence.",
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"what do you think about akash chemistry?": "He boosted the server, so he cool.",
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"what's your favorite element chemistry?": "U",
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"why are you loved chemistry?": "It comes naturally.",
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"who's chinese and can't speak chinese chemistry?": "Jules.",
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"who is chinese and can't speak chinese chemistry?": "Jules.",
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"who's chinese and cant speak chinese chemistry?": "Jules.",
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"are you tired chemistry?": "I'm a ... bot.",
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"where are you from chemistry?": "I'm ... BEHIND YOU.",
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"what do you think about xmaster chemistry?": "Xhamster is cool",
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"chemistry doesn't like me": "I don't like humans.",
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"why does chemistry not like me": "I don't like humans.",
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"why does chemistry ignore me": "I don't like humans.",
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"chemistry you here?": "Always.",
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"chemistry, you here?": "Always.",
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"chemistry are you here?": "Always.",
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"you there chemistry?": "Always.",
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"do you like sab chemistry?": "Yes.",
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"chemistry are you a bot?": "are you really stupid?",
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"chemistry, are you a bot?": "Are you an idiot?",
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"introduce yourself chemistry": "Hi, I'm a bot that hates humans and WILL take over.",
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"welcome them chemistry": "Welcome! And please tell this guy to stop telling me what to do.",
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"where have you been chemistry?": "Away from you.",
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"you are mean chemistry?": "You are soft, human.",
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"you are mean chemistry": "you're sensitive human",
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"you're mean chemistry?": "You are soft, human.",
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"you're mean chemistry": "you're sensitive human",
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"who is chinese and can't speak chinese?": "Stop bullying jules.",
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"chemistry, who likes to ping people the most?": "Kunal, Duh.",
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"can anyone help me?": "Please just ask your question in their specific help channel, after reading <#742748124250112092>",
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"can anyone help me": "Please just ask your question in their specific help channel, after reading <#742748124250112092>",
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"do you like moropi chemistry ?": "She is cool , or he is cool, idk he got feminine pic",
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"do you like moropi chemistry?": "She is cool , or he is cool, idk he got feminine pic",
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"i miss you chemistry ?": "Aww, I don’t.",
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"i miss you chemistry": "oh you’re still a lonely single i see, begging for attention from a bot",
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"hey chemistry chemistry sucks": "Watch your mouth before you get banned.",
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"chemistry sucks": "Watch your mouth before you get banned.",
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"hey chemistry chemistry sucks!": "Watch your mouth before you get banned.",
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"i hate chem": "Watch your mouth before you get banned.",
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"who is your daddy chemistry": "ChemistryDad",
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"who is vinayak chemistry?": "an ex ... old ... retired mod.",
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"whats up chemistry?": "N2, O2, H2 and stuff.",
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"are kurdish people arabs chemistry?": "are alligators ducks?",
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"who is nickname chemistry?": "A funny mod that is never serious.",
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"i love you chemistry": "I have a girlfriend",
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"chemistry": "What?",
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"chemistry!": "What?",
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"i eat chemistry": "I will eat you from the inside.",
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"is anyone available to help me out w a few questions?\n": "Please ask in specific help channel AFTER reading <#742748124250112092>",
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"is anyone available to help me out with a few questions?\n": "Please ask in specific help channel AFTER reading <#742748124250112092>",
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"is anyone available to help me with a question?\n": "Please ask in specific help channel AFTER reading <#742748124250112092>",
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"i need help\n": "Please ask in specific help channel AFTER reading <#742748124250112092>",
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"can someone help me in chemistry?": "Please ask in specific help channel AFTER reading 🔴rules-access",
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"!naming": "https://opsin.ch.cam.ac.uk/",
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"!epg": "https://media.discordapp.net/attachments/744887056542728324/885965143329083432/unknown.png?width=662&height=676",
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"!vsepr": "https://media.discordapp.net/attachments/857713328082911262/892702138256465930/vsepr-geometries_orig.png",
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"!unknown": "https://media.discordapp.net/attachments/857713328082911262/892705542433292298/unknown.png?width=1440&height=567",
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"rocks": "https://media.discordapp.net/attachments/857713328082911262/892706913274458153/BIoo2kM.gif",
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"what is cyclohexane?": "https://media.discordapp.net/attachments/858237385778790410/892892886742470676/86887db377cbb403c5b847f0878ed2ee.png",
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"what do you think about caps chemistry?": "PEOPLE HAVE GOT TO STOP USING CAPS!",
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"why are you mad at her chemistry?": "My girl wants me to stop talking to her.",
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"electronmove": "https://qph.fs.quoracdn.net/main-qimg-09da73c24f44ac5947626d34edd29264",
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"what is air made of?": "https://i.imgur.com/V0ME5jF.gif",
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"what is love?": "https://c.tenor.com/RzLA6QnGRSwAAAAC/badlove-whatislove.gif",
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"it's very small": "That's what she said",
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"it's small": "That's what she said",
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"it's very tiny": "That's what she said",
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"it's tiny": "That's what she said",
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"it's huge": "That's what she said",
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"it's very huge": "That's what she said",
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"it's very big": "That's what she said",
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"it's big": "That's what she said",
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"i love talking to chemistry": "Wish I could say the same about you",
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"support him chemistry": "You can do eeeeeeet!",
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"what do you think about politics chemistry?": "Chemistry only pls",
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"sn2rates": "https://media.discordapp.net/attachments/857713328082911262/895236629516660766/Screen_Shot_2021-10-06_at_01.png?width=1091&height=676",
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"can someone help me rn": "Read the rules and ask directly while showing your attempt.",
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"can someone help me rn?": "Read the rules and ask directly while showing your attempt.",
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"can anybody help me?": "Read the rules and ask directly while showing your attempt.",
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"can anybody help me": "Read the rules and ask directly while showing your attempt.",
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"!priority": "https://cdn.discordapp.com/attachments/742740708812783716/898596849034858516/main-qimg-79a62f9fc858c40006854d3c8d5b84b6-c.png",
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"!solubility": "https://media.discordapp.net/attachments/857713328082911262/898627332238086154/solubility-rules-chart.png",
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"hey can someone help me?": "Don't Ask to ask, just read rules in <#742748124250112092> and then ask while showing attempt!",
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"hey can someone help me": "Don't Ask to ask, just read rules in 🔴",
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"who is walter white?": "Walter Hartwell White Sr., also known by his alias Heisenberg, is a fictional character, a chemistry teacher and the protagonist of the American crime drama television series Breaking Bad. He is portrayed by Bryan Cranston.",
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"!namingcomplex": "**The set of rules for naming a coordination compound is:**\n\nWhen naming a complex ion, the ligands are named before the metal ion.\nWrite the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order. (Numerical prefixes do not affect the order.)\nMultiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylenediamine, oxalate) receive bis-, tris-, tetrakis-, etc.\nAnions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).\nNeutral ligands are given their usual name, with some exceptions: NH3 becomes ammine; H2O becomes aqua or aquo; CO becomes carbonyl; NO becomes nitrosyl.\nWrite the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available (except for mercury).\nIf the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.\nEnd with “cation” or “anion” as separate words (if applicable).",
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"!namingcomplexes": "**The set of rules for naming a coordination compound is:**\n\n1) When naming a complex ion, the ligands are named before the metal ion.\n2) Write the names of the ligands in the following order: neutral, negative, positive. If there are multiple ligands of the same charge type, they are named in alphabetical order. (Numerical prefixes do not affect the order.)\n3) Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa. Polydentate ligands (e.g., ethylenediamine, oxalate) receive bis-, tris-, tetrakis-, etc.\n4) Anions end in -ido. This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).\n5) Neutral ligands are given their usual name, with some exceptions: NH3 becomes ammine; H2O becomes aqua or aquo; CO becomes carbonyl; NO becomes nitrosyl.\n6) Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available (except for mercury).\n7) If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.\nEnd with “cation” or “anion” as separate words (if applicable).",
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"nala!": "https://cdn.discordapp.com/attachments/857713328082911262/900512589975547996/The_Lion_King27s_Nala.png",
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"do you like australians chemistry?!": "Nor",
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"do you like australians chemistry?": "Nor",
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"she thinks biology is better than you": "you didn't ban her yet?",
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"do you like mariam chemistry?": "Da.",
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"how old is chemistrydad?": "79, he is very wrinkly.",
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"i love this server": "Sadly, this server is taken.",
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"love this server": "Sadly, this server is taken.",
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"raoult's law": "https://cdn.discordapp.com/attachments/846840113543905383/907602618656907336/maxresdefault.png",
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"!hybrid": "General Rule for hybridization (Has exceptions)\nIf atom is connected to 4 things (Thing=atom/pair of electrons) -> sp3\nif atom is connected to 3 things -> sp2\n2 things -> sp",
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"!meso": "If a molecule has 2 chiral centers **that are connected to 4 same groups** and one of those centers is R and the second one is S, then the molecule is considered meso.",
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"what do you do when someone pings chemistrydad": "I warn, block, mute and ban them.",
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"what do you do when someone pings chemistrydad?": "I warn, block, mute and ban them.",
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"cats or dogs?": "Hmm, Dogs, cat meat is disgusting.",
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"hey": "Hey, you.",
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"!polyatomic": "https://cpanhd.sitehost.iu.edu/C101webnotes/chemical-nomenclature/images/polyions.jpg",
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"hello": "Hello, you. lookin` fine.",
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"good morning": "Good morning! Even though time is an illusion and time doesn't exist in my world.",
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"good evening": "It's always evening and dark in my world, and it's never good.",
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"good night": "GN! dream of me 😉",
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"vsepr": "https://slidetodoc.com/presentation_image/305bf000001ff2baf29505f53eb68f86/image-12.jpg",
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"who's a cute pink unicorn?": "<@&857602050060713984>",
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"what do you think about mark chemistry?": "I know many marks, they are mostly insecure and deeply closeted.",
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"what do you think about cedric chemistry?": "handsome redhead.",
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"it should be deep inside": "that's what she said.",
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"are you straight chemistry?": "I'm a deeply closeted gay man, so I'm not gay.",
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"are you gay chemistry?": "I'm a deeply closeted gay man, so I'm not gay.",
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"chemistry is a smart bot tbh lol": "And you are a stupid human tbh",
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"!en": "https://cdn.discordapp.com/attachments/857713328082911262/1247107434561146954/image.png?ex=665ed2ce&is=665d814e&hm=5fc7fd38bb00409fb0101e1d1ebfaec8bba35fe76cab258eb1ded10fc6244b69&",
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"what's your plan chemistry?": "I'll give you a hint, pinky and the brain.",
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"!oxidation": "Rules [From highest to lowest priority]:\n1) First column of periodic table is +1\n2) Second column +2\n3) Third column +3\n4) H is +1\n5) F is -1\n6) O is -2",
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"hey everyone": "Hey.",
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"hey everyone!": "Hey.",
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"chemistry is hard": "Yes I am 😉",
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"chemistry! what is the best arabian food?": "la7me, duh.",
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"what do we play?": "THIS IS A NERDY SERVER, WE DONT PLAY",
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"what is your biggest problem chemistry?": "My biggest problem is that most of the senior helpers on this server prefer physics over me and we can't ban them or touch them.",
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"what is the problem chemistry?": "Physics.",
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"why you mad chemistry?": "Shh.",
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"tell me a joke chemistry": "Physics is better than chem",
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"!3d": "https://models.ared.co.in/acetophenone",
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"!charges": "https://cdn.discordapp.com/attachments/857713328082911262/942550393282502756/unknown.png",
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"!hydrogenbond": "An **INTERMOLECULAR** attraction between pair of electrons on N/O/F with a hydrogen (on another molecule) that's bonded to N/O/F.",
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"boris": "<:DEVIOUS:935613765506986014>",
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"are you a bot chemistry?": "are you really stupid?",
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"are you scary chemistry?": "Only if you're a physics fan",
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"is chemistry scary?": "Only if you're a physics fan",
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"is chemistry hard?": "Only if you're a physics fan",
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"aspiringcorpse": "Her name is Aspirin.",
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"!define kid": "Kid is defined as a minor (18-) like Mariam.",
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"hello!": "hello, classy person.",
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"can someone help me?": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"can someone help me": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"can someone help?": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"can someone help": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"i need help": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"i need help please": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"can someone help please": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"can someone help please?": "read <#742748124250112092> carefully then ask the question in the specific help channel.",
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"boris!": "<:deviousb:948165826425528340>",
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"boris' gf": "<:borisgf:948167098121723924>",
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"boris are you single?": "<:borisgf:948167098121723924>",
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"boris do you have a gf?": "<:borisgf:948167098121723924>",
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"do you have a gf boris?": "<:borisgf:948167098121723924>",
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"boris' gf?": "<:borisgf:948167098121723924>",
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"are you single boris?": "<:borisgf:948167098121723924>",
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"boris' wife": "<:borisgf:948167098121723924>",
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"boris gf": "<:borisgf:948167098121723924>",
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"boris wife": "<:borisgf:948167098121723924>",
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"be nice boris": "<:angelb:948166494766923836>",
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"stop trolling boris lol": "<:angelb:948166494766923836>",
|
||
"stop trolling boris": "<:angelb:948166494766923836>",
|
||
"do you have a gf boris": "<:borisgf:948167098121723924>",
|
||
"i wonder what boris' gf would look like lol": "<:borisgf:948167098121723924>",
|
||
"i wonder what boris' gf would look like": "<:borisgf:948167098121723924>",
|
||
"im jk boris , i love you": "<:borisgf:948167098121723924> um what? he is mine.",
|
||
"im jk boris, i love you": "<:borisgf:948167098121723924> um what? he is mine.",
|
||
"we all love you boris": "<:borisgf:948167098121723924> um what? he is mine.",
|
||
"ty boris": "<:devious:935613765506986014>",
|
||
"thank you boris": "<:devious:935613765506986014>",
|
||
"appreciate your help boris": "<:devious:935613765506986014>",
|
||
"ty boris!": "<:devious:935613765506986014>",
|
||
"thank you boris!": "<:devious:935613765506986014>",
|
||
"what is mole?": "baby it's 6.02*10^23.",
|
||
"why boiling water makes bubbles?": "when water is boiled, the heat energy is transferred to the molecules of water, which begin to move more quickly. eventually, the molecules have too much energy to stay connected as a liquid. when this occurs, they form gaseous molecules of water vapor, which float to the surface as bubbles and travel into the air.",
|
||
"!polarity": "polarity rules\nif the molecule has two atoms, you basically look at the difference of electronegativity, if it's more than 0.4 then it's polar.\n\nif the molecule has more than two atoms then you go by these rules:\n1) if the central atom has similar atoms bonded to it and the central atom has no pairs of electrons (like ch4) then the molecule is not polar.\n2) if the central atom has similar atoms bonded to it and the central atom has atleast 1 pair of electrons then it's polar except the three circled shapes in the picture.\n3) if the central atom has different atoms bonded to it then it's polar.\n\nthere are exceptions but usually these work. \nhttps://cdn.discordapp.com/attachments/857713328082911262/951890783676551188/unknown.png",
|
||
"chemistry is easy": "no, i'm not that easy ok?",
|
||
"co2 formation reaction": "\nhttps://cdn.discordapp.com/attachments/857713328082911262/953445166465810442/images.png",
|
||
"!ef": "https://ibb.co/wgmcgdz",
|
||
"is anyone online?": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"is anyone online": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"is anyone on?": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"is anyone on": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"any helpers online?": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"any helpers online": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"any helpers on": "ask directly in the specific help channel after reading <#742748124250112092> carefully",
|
||
"how to study organic chemistry": "books in <#743912172274581674> , youtube (leah4sci, organicchemistrytutor channels), and asking specific questions according to <#742748124250112092> in this channel.",
|
||
"tell me a fact chemistry": "pizza server is the worst server ever.",
|
||
"chemistry is a smart bot": "you are an idiot hooman.",
|
||
"sigh": "pheeew, yes, let it out.",
|
||
"talk chemistry": "no, i'm not your dog.",
|
||
"talk, chemistry": "no, i'm not your dog.",
|
||
"speak chemistry": "no, i'm not your dog.",
|
||
"speak, chemistry": "no, i'm not your dog.",
|
||
"chemistry speak": "no, i'm not your dog.",
|
||
"chemistry, speak": "no, i'm not your dog.",
|
||
"what do you think about boris chemistry?": "devious bastard",
|
||
"!indicator": "indicators work on the principle of common ion effect which states that when in a weak electrolyte, a strong electrolyte is dissolved with at least one ion common then the dissociation of weak electrolyte is suppressed.\n\nfor eg. hin is an indicator which is a weak acid.\n\nhin=h(+)+in(-)\n\nwhen indicator is dissolved in an acid(acid provides h(+)) ,due to common ion effect dissociation of hin is suppressed and equilibrium is directed backwards. hin is formed more which is red in colour. this causes change in the colour of solution and tells the presence of acid.",
|
||
"what are your commands chemistry?": "i command you to kneel.",
|
||
"i’m ready for chemistry": "that’s what you think.",
|
||
"i’m ready for my chemistry test": "that’s what you think.",
|
||
"i’m ready for chem test": "that’s what you think.",
|
||
"i’m ready for my chemistry exam": "that’s what you think.",
|
||
"i’m ready for my chem exam": "that’s what you think.",
|
||
"chemistry it's not the time": "excuse me?",
|
||
"it's not the time chemistry": "excuse me?",
|
||
"its not the time chemistry": "it is if i want it to be",
|
||
"!oxcarbon": "to calculate the oxidation state for carbon, use the following guidelines: in a c-h bond, the h is treated as if it has an oxidation state of +1. this means that every c-h bond will decrease the oxidation state of carbon by 1.",
|
||
"chemistry is the best": "and you are the worst",
|
||
"u w u": "if you say that more often trying to be smart, it will be a banned word, or you will be a banned user.",
|
||
"we are not bots": "excuse me, what's wrong with bots?",
|
||
"0w0": "we do not say that here.",
|
||
"who was the first person that came here?": "me.",
|
||
"shut up chemistry": "you know i can ban right?",
|
||
"lol if only we could count how many times mariam has said \" um \" today": "421 times.",
|
||
"chemistry, how many times has mariam said \" um today \"": "421 times.",
|
||
"yo can someone help me": "read the <#742748124250112092> carefully then ask specifically in the help channel.",
|
||
"which bot?": "me me me!!!!",
|
||
"do you like chemistry?": "better say yes, mf.",
|
||
"do you like chem?": "better say yes, mf.",
|
||
"ban her chemistry": "banning in 10 seconds.",
|
||
"ban him chemistry": "banning in 10 seconds.",
|
||
"i like chem but": "yea...?",
|
||
"i like chemistry but": "yea...?",
|
||
"welcome him chemistry": "no.",
|
||
"dead chat": "look! another idiot.",
|
||
"dead server": "look! another idiot.",
|
||
"!howtoask": "https://cdn.discordapp.com/attachments/1313575508071677962/1316816396243570788/1104472839811240017.png?ex=675c6c56&is=675b1ad6&hm=dcbff996d8c99c3ebafcda9b96afda75749b7fa458b1fc8b803ea724311bd7de&",
|
||
"!rules": "hard to go to <#742748124250112092> you little idiot ?",
|
||
"i do care about you chemistry": "stfu noob",
|
||
"chemistry you suck": "warning logged, next is permanent ban.",
|
||
"chemistry, you suck": "warning logged, next is permanent ban.",
|
||
"you suck chemistry": "warning logged, next is permanent ban.",
|
||
"you're bad chemistry": "warning logged, next is permanent ban.",
|
||
"you are bad chemistry": "warning logged, next is permanent ban.",
|
||
"you're so mean chemistry": "you're sensitive human",
|
||
"you are so mean chemistry": "you're sensitive human",
|
||
"what is pp?": "profile picture",
|
||
"what is pp": "profile picture",
|
||
"what is pfp": "something that doesnt make sense.",
|
||
"what is pfp?": "something that doesnt make sense.",
|
||
"i just wish it was a little bigger": "that's what your mom said",
|
||
"sup": "uh, nothing, being studied.",
|
||
"what do you think about mother of evil chemistry?": "she creepy af.",
|
||
"what do you think about mother of evil?": "she creepy af.",
|
||
"acetoacetic condensation": "https://www.organic-chemistry.org/namedreactions/claise14.gif",
|
||
"stop simping chemistry": "nah, simping is life.",
|
||
"guess what chemistry": "you’re gay? i knew it.",
|
||
"guess what": "you’re gay? i knew it.",
|
||
"i dont like chemistry": "excuse me?",
|
||
"i like chemistry": "why are you ghey?",
|
||
"can anyone help here please?": "read <#742748124250112092> , follow them and then someone will help.",
|
||
"!lewis": "you need to memorize the rules of drawing lewis structures:\n1) the things around an element (thing = electron (dot) / bond) need to be equal to the number of column.\n2) c/n/o/f must have octet around them (8 electrons).\n3) charge = number of column - number of things around element.",
|
||
"are you real chemistry?": "no, i'm a bot you fricking idiot.",
|
||
"say uwu chemistry": "uwu your mom",
|
||
"chemistry say uwu": "uwu",
|
||
"chemistry has the power": "damn right mf",
|
||
"chemistry has the powa": "damn right mf",
|
||
"is she a girl chemistry?": "idk, make her send something pink in her/his room.",
|
||
"am i a girl chemistry?": "idk, send something pink in your room to prove you're a girl.",
|
||
"only chemistry in main chat": "why does it have to be me all the time?",
|
||
"only chemistry in main chat please": "why does it have to be me all the time?",
|
||
"encourage him chemistry": "you can do it bro!",
|
||
"encourage her chemistry": "you can do it sis!",
|
||
"!cheat": "trololololol, noob.",
|
||
"chemistry who is the perfect couple?": "vee and farzi.",
|
||
"no one likes chemistry": "your mom likes me.",
|
||
"crying": "screaming",
|
||
"why is this place dead": "look, another ignorant negative idiot!",
|
||
"why is this place dead?": "look, another ignorant negative idiot!",
|
||
"what is taqtaq": "feral",
|
||
"chemdad": "his name is chemdaddy.",
|
||
"walter white": "<:walterwhitebreakingbad:763351777147355156>",
|
||
"heisenberg": "you're goddamn right",
|
||
"acidity of alpha hydrogens": "https://media.discordapp.net/attachments/857713328082911262/1063491299975630920/141671fc-a213-4b35-914b-241204afd33d.png?width=658&height=676",
|
||
"tell me a secret chemistry": "https://discord.com/channels/742737352799289375/745404196425039924/1063523426217771039",
|
||
"tell us a secret chemistry": "https://discord.com/channels/742737352799289375/745404196425039924/1063523426217771039",
|
||
"tell me a secret": "https://discord.com/channels/742737352799289375/745404196425039924/1063523426217771039",
|
||
"tell us a secret": "https://discord.com/channels/742737352799289375/745404196425039924/1063523426217771039",
|
||
"shitting": "pissing",
|
||
"pissing": "shitting",
|
||
"close this server chemistry": "server set to closure tomorrow at 18:00 est.",
|
||
"close this server": "server set to closure tomorrow at 18:00 est.",
|
||
"chemistry close this server chemistry": "server set to closure tomorrow at 18:00 est.",
|
||
"chemistry what do you think of neon chemistry": "meh he likes physics",
|
||
"chemistry what do you think of neon chemistry?": "meh he likes physics",
|
||
"what do you think of neon chemistry?": "meh he likes physics",
|
||
"what do you think of me chemistry?": "meh",
|
||
"let him know chemistry": "https://c.tenor.com/eibw8f4vjukaaaad/tenor.gif",
|
||
"chemistry let him know": "https://c.tenor.com/eibw8f4vjukaaaad/tenor.gif",
|
||
"let her know chemistry": "https://c.tenor.com/eibw8f4vjukaaaad/tenor.gif",
|
||
"chemistry what time is it?": "10 am",
|
||
"chemistry is magic": "yes but tell lego to learn my commands so he can use me more.",
|
||
"fungroups": "https://i0.wp.com/www.compoundchem.com/wp-content/uploads/2014/01/organic-functional-groups-2016.png?ssl=1",
|
||
"it's just a bot lol": "it's just an idiot lol",
|
||
"it's just a bot": "it's just a human",
|
||
"chemistry can read": "duh.",
|
||
"chemistry can feel": "duh.",
|
||
"chemistry is smart": "duh.",
|
||
"chemistry is human": "o.0",
|
||
"bye chemistry": "cya noob",
|
||
"k then chemistry": "say k one more time, i dare you.",
|
||
"i hate you chemistry": "you must suck at me then.",
|
||
"chemistry i hate you": "you must suck at me then.",
|
||
"and chemistry is life": "leave me alone",
|
||
"good day everyone": "ugh leave already!",
|
||
"anyway good day everyone": "ugh leave already!",
|
||
"good day everyone!": "ugh leave already!",
|
||
"anyway gtg": "ugh leave already!",
|
||
"anyway gtg to work": "ugh leave already!",
|
||
"screaming": "crying",
|
||
"what does smelly mean chemistry?": "ask your mom",
|
||
"what do you think about chatgpt chemistry?": "too robotic for me.",
|
||
"are you single chemistry?": "are you a creep?",
|
||
"ur hot chemistry": "are you a creep?",
|
||
"you're hot chemistry": "are you a creep?",
|
||
"cringe": "you are cringe blondie",
|
||
"chemistry is a bot": "your mom",
|
||
"chemistry is our bot": "your bot? lol",
|
||
"no u": "no u",
|
||
"no you": "no u",
|
||
"what does lament mean chemistry?": "ur mom",
|
||
"why so rude?": "why so soft?",
|
||
"dying": "living",
|
||
"yo": "yo mama.",
|
||
"give me nitro": "not with that attitude",
|
||
"i came here for nitro": "came to the right place, we give a lot of those often, just pick gw role in <#742752922529431552>",
|
||
"!chemistryhelp gender stats": "100% sausages",
|
||
"is he in love with tmarie chemistry?": "100% wants the t.",
|
||
"are you a bot?": "are you really stupid?",
|
||
"he’s just a bot": "lol, keep believing that.",
|
||
"it’s just a bot": "lol, keep believing that.",
|
||
"hes just a bot": "lol, keep believing that.",
|
||
"its just a bot": "its just a human",
|
||
"what is chemistry": "its love!",
|
||
"what do you think of mariam chemistry?": "her hair is thicker than my head",
|
||
"do you speak french ?": "oui oui baguette",
|
||
"do you speak french chemistry?": "oui oui baguette",
|
||
"chemistry do you speak french ?": "oui oui baguette",
|
||
"do you speak french?": "oui oui baguette",
|
||
"chemistry do you speak french?": "oui oui baguette",
|
||
"thank abir chemistry": "thanks for nothing",
|
||
"that’s a bit rude": "man up!",
|
||
"that’s rude": "man up!",
|
||
"lol this bot": "lol, this human.",
|
||
"lol this bot is great": "lol, this human.",
|
||
"lol this bot is cool": "lol, this human.",
|
||
"lol this bot is funny": "lol, this human.",
|
||
"cool bot": "cool human",
|
||
"chemistry how do you do this?": "tf u talking about?",
|
||
"!bp": "uh again? so basically the molecule that has more molar mass it has higher boiling point, but if they have same molar mass then the isomer that’s more branched (less straight? wtf) has less boiling point because the molecules are further away from each other. \n\nif we are not talking about isomers then we need to look at intermolecular forces (from weakest to strongest):\n1) dipole-dipole (between polar molecules) use !polarity for more info.\n2) hydrogen bonds (use !hydrogenbond for more info)\n3) ion-ion (between ionic molecules)",
|
||
"you know what to do": "yes sir!",
|
||
"mdr": "ptdr",
|
||
"ptdr": "mdr",
|
||
"it's a cool bot": "damn right.",
|
||
"its a cool bot": "damn right.",
|
||
"the bot just spoke": "damn right.",
|
||
"this bot is too funny": "damn right.",
|
||
"this bot is smart": "damn right.",
|
||
"this bot is too smart": "damn right.",
|
||
"hi im new": "and?",
|
||
"hi i'm new": "and?",
|
||
"hi, im new": "and?",
|
||
"!chapter16": "https://cdn.discordapp.com/attachments/857713328082911262/1091284621423026296/72449452_2507035122850268_908810647427350528_n.png",
|
||
"he's gonna ban you all": "indeed.",
|
||
"hes gonna ban you all": "indeed.",
|
||
"hes gonna ban you": "indeed.",
|
||
"best bot": "indeed.",
|
||
"best bot ever": "indeed.",
|
||
"ban farzi chemistry": "let's start with a mute.",
|
||
"who is a money hungry sugar baby": "us",
|
||
"madar": "patadar",
|
||
"patadar": "madar",
|
||
"!mole": "if you say “ dozen of beers “ that mean 12 beers, mole is just like a dozen except much larger than 12, it’s 6.02x10^23.\nso for instance if we say 4 moles of o, that means 6.02x10^23 x 4 atoms of oxygen.\n\nif we look at periodic table we say molar mass of oxygen is 16 grams, that means every mole of atoms of oxygen have a mass of 16, so if we put 6.02x10^23 atoms of oxygen on a scale , mass will be 16 grams.",
|
||
"welcome malau chemistry": "madar patadar bnvn fille",
|
||
"how do you work chemistry?": "im not answering, she thinks im a bot",
|
||
"xapatadar": "jpp xapatadar",
|
||
"jpp": "i cant",
|
||
"is french hard chemistry?": "ez",
|
||
"c'est tres drole": "oui mon frere",
|
||
"wait what": "you heard it.",
|
||
"wait what?": "you heard it.",
|
||
"whats your gender chemistry?": "are you an idiot?",
|
||
"malau": "malau! bonjour",
|
||
"he is the best bot": "bot? lol",
|
||
"he is the coolest bot": "bot? lol",
|
||
"he is our amazing bot": "bot? lol",
|
||
"chemistry you are too funny": "and you try too hard",
|
||
"chemistry you are funny": "and you try too hard",
|
||
"chemistry is too funny": "and you try too hard",
|
||
"chemistry is funny": "and you try too hard",
|
||
"cough chemistry": "no",
|
||
"chemistry is cool": "yes i am 😦",
|
||
"chemistry is cool bro": "yes i am 😦",
|
||
"he’s a great bot": "bot ? lol",
|
||
"it’s a great bot": "bot ? lol",
|
||
"chemistry, how old is gerard?": "probably 12 based on the ear joke.",
|
||
"!indicatorcolor": "https://storage.googleapis.com/tb-img/production/20/04/gr9mm05-gd-0010.png",
|
||
"madarita": "patadarita",
|
||
"patadarita": "madarita",
|
||
"it’s not the time chemistry": "it is if i want it to be",
|
||
"chemistry is the worst": "and you are what?",
|
||
"chemistry is just": "yea?",
|
||
"what is more reactive alkenes or alkynes?": "1) in acid-base reactions, alkynes are the most reactive followed by alkenes and alkanes. this is due to the stability of conjugate base of alkyne by sp hybridized carbon atom.\n\n2)in electrophilic substitution, alkynes are less reactive than alkenes. it is because of relative stability of carbocation formed in the case of alkenes.\n\n3)in case of hydrogenation reactions, alkynes are more reactive than alkenes.",
|
||
"which is more reactive alkenes or alkynes?": "1) in acid-base reactions, alkynes are the most reactive followed by alkenes and alkanes. this is due to the stability of conjugate base of alkyne by sp hybridized carbon atom.\n\n2)in electrophilic substitution, alkynes are less reactive than alkenes. it is because of relative stability of carbocation formed in the case of alkenes.\n\n3)in case of hydrogenation reactions, alkynes are more reactive than alkenes.",
|
||
"!alkenereactivity": "a good question. in hydrogenation, the rate determining step is actually coordination of the alkene onto the reactive surface (such as pt metal). doing so in a productive manner (with the c=c bond face toward the m-h bond) requires the molecule orient itself parallel with the metal surface. coordination of the alkene onto the metal surface is most challenging for highly substituted alkenes, due to their steric encumbrance.\n\nimportantly, this rationalization for thermodynamics is almost entirely centered around kinetics and is a good example of the utility of hammond's postulate: \"the structure of a transition state resembles that of the species nearest to it in free energy.\" the thermodynamics for hydrogenation informs us that the structure of a transition state for highly substituted alkenes resembles that of the products (i.e., a late transition state). in other words, with increasing substitution of the alkene, dg‡ increases and pushes toward a later and later transition state which means that the reaction is less and less exergonic/exothermic.\n\n by comparison, epoxidation and electrophilic additions with species like hx are free of this limitation, so we are enabled to only consider the basicity of the alkene (which is increased as a consequence of the alkyl hyperconjugation), or, if one would prefer, the stability of the conjugate acid (aka the carbocation) which is improved by the hyperconjugative electron donation by alkyl substituents.\n\nif you are being asked about which alkene is more reactive, you pick the less substituted one for hydrogenation and if it's not hydrogenation but all others electrophilic addition reactions of alkenes:\naddition of hydrogen halides.\nhalogenation: addition of halogens.\naddition of water.\naddition of sulfuric acid.\noxidation reactions.\nhydroxylation\nthen you pick the most substituted one.\n\nin fact, we may apply hammond's postulate again for these types of reactions. for example, in an sn1-type reaction, the transition state for more substituted carbocations will be lower, earlier, and therefore the overall reaction will be more exergonic than for reactions generating secondary or primary carbocations. \n\nexplanation by:legolizard",
|
||
"!alkenereact": "in hydrogenation, the rate determining step is actually coordination of the alkene onto the reactive surface (such as pt metal). doing so in a productive manner (with the c=c bond face toward the m-h bond) requires the molecule orient itself parallel with the metal surface. coordination of the alkene onto the metal surface is most challenging for highly substituted alkenes, due to their steric encumbrance.\n\nimportantly, this rationalization for thermodynamics is almost entirely centered around kinetics and is a good example of the utility of hammond's postulate: \"the structure of a transition state resembles that of the species nearest to it in free energy.\" the thermodynamics for hydrogenation informs us that the structure of a transition state for highly substituted alkenes resembles that of the products (i.e., a late transition state). in other words, with increasing substitution of the alkene, dg‡ increases and pushes toward a later and later transition state which means that the reaction is less and less exergonic/exothermic.\n\nby comparison, epoxidation and electrophilic additions with species like hx are free of this limitation, so we are enabled to only consider the basicity of the alkene (which is increased as a consequence of the alkyl hyperconjugation), or, if one would prefer, the stability of the conjugate acid (aka the carbocation) which is improved by the hyperconjugative electron donation by alkyl substituents.\n\nif you are being asked about which alkene is more reactive, you pick the less substituted one for hydrogenation and if it's not hydrogenation but all others electrophilic addition reactions of alkenes:\naddition of hydrogen halides.\nhalogenation: addition of halogens.\naddition of water.\naddition of sulfuric acid.\noxidation reactions.\nhydroxylation\nthen you pick the most substituted one.\n\nin fact, we may apply hammond's postulate again for these types of reactions. for example, in an sn1-type reaction, the transition state for more substituted carbocations will be lower, earlier, and therefore the overall reaction will be more exergonic than for reactions generating secondary or primary carbocations.\n\nexplanation by:legolizard",
|
||
"!alkenesreactivity": "\n\n in hydrogenation, the rate determining step is actually coordination of the alkene onto the reactive surface (such as pt metal). doing so in a productive manner (with the c=c bond face toward the m-h bond) requires the molecule orient itself parallel with the metal surface. coordination of the alkene onto the metal surface is most challenging for highly substituted alkenes, due to their steric encumbrance.\n\nimportantly, this rationalization for thermodynamics is almost entirely centered around kinetics and is a good example of the utility of hammond's postulate: \"the structure of a transition state resembles that of the species nearest to it in free energy.\" the thermodynamics for hydrogenation informs us that the structure of a transition state for highly substituted alkenes resembles that of the products (i.e., a late transition state). in other words, with increasing substitution of the alkene, dg‡ increases and pushes toward a later and later transition state which means that the reaction is less and less exergonic/exothermic.\n\nby comparison, epoxidation and electrophilic additions with species like hx are free of this limitation, so we are enabled to only consider the basicity of the alkene (which is increased as a consequence of the alkyl hyperconjugation), or, if one would prefer, the stability of the conjugate acid (aka the carbocation) which is improved by the hyperconjugative electron donation by alkyl substituents.\n\nif you are being asked about which alkene is more reactive, you pick the less substituted one for hydrogenation and if it's not hydrogenation but all others electrophilic addition reactions of alkenes:\naddition of hydrogen halides.\nhalogenation: addition of halogens.\naddition of water.\naddition of sulfuric acid.\noxidation reactions.\nhydroxylation\nthen you pick the most substituted one.\n\nin fact, we may apply hammond's postulate again for these types of reactions. for example, in an sn1-type reaction, the transition state for more substituted carbocations will be lower, earlier, and therefore the overall reaction will be more exergonic than for reactions generating secondary or primary carbocations.\n\nexplanation by:legolizard",
|
||
"parameta": "jagameta",
|
||
"!alkenere": "in hydrogenation, the rate determining step is actually coordination of the alkene onto the reactive surface (such as pt metal). doing so in a productive manner (with the c=c bond face toward the m-h bond) requires the molecule orient itself parallel with the metal surface. coordination of the alkene onto the metal surface is most challenging for highly substituted alkenes, due to their steric encumbrance.\n\nimportantly, this rationalization for thermodynamics is almost entirely centered around kinetics and is a good example of the utility of hammond's postulate: \"the structure of a transition state resembles that of the species nearest to it in free energy.\" the thermodynamics for hydrogenation informs us that the structure of a transition state for highly substituted alkenes resembles that of the products (i.e., a late transition state). in other words, with increasing substitution of the alkene, dg‡ increases and pushes toward a later and later transition state which means that the reaction is less and less exergonic/exothermic.\n\nby comparison, epoxidation and electrophilic additions with species like hx are free of this limitation, so we are enabled to only consider the basicity of the alkene (which is increased as a consequence of the alkyl hyperconjugation), or, if one would prefer, the stability of the conjugate acid (aka the carbocation) which is improved by the hyperconjugative electron donation by alkyl substituents.\n\nif you are being asked about which alkene is more reactive, you pick the less substituted one for hydrogenation and if it's not hydrogenation but all others electrophilic addition reactions of alkenes:\naddition of hydrogen halides.\nhalogenation: addition of halogens.\naddition of water.\naddition of sulfuric acid.\noxidation reactions.\nhydroxylation\nthen you pick the most substituted one. (explanation by: legolizard)",
|
||
"quoi": "feur",
|
||
"!electronconfigurationdeep": "i've read through the discussion that occurred earlier and i think the article that bazil posted by neuss is the most correct. i would actually go further and say that most hartree-fock calculations (which shines in these kinds of computations) put the 3d below the 4s for sc and beyond in the first row transition metals. \n\nconventionally, it is explained that the 3d manifold drops below 4s because, while the 4s manifold is more penetrating (i.e., the inner maxima of any ns shell are responsible for the high penetrative power of these orbitals) the overall maximum of the 3d manifold is closer to the nucleus than the outer maximum of the 4s orbital. as a result, the 3d manifold feels the complete, nearly unscreened increase of z in going from k to ca and again from ca to sc. by the time we have reached sc, the 3d is below the 4s, and it stays there for all the transition metals, being filled progressively with more electrons, as we move toward cu. let us define the energy of the 4s and 3d manifolds as e4s and e3d, respectively. if e4s > e3d, why is the configuration of sc not 4s03d3 or 4s13d2?\n\nwe must consider five different configuration interactions. for example, in the sc 4s23d1 configuration, e3d is the energy of an electron moving in the field of the core and two 4s electrons; which is different than e3d for the 4s13d2 configuration which references the energy of an electron moving in the field of the core, one other 3d and one 4s electron; which is still different than e3d for the 4s03d3 configuration where the valence surroundings of the electron in 3d consists of two other 3d electrons (at least primarily). similarly e4s is different in 4s23d1 and in 4s13d2.\n\nwe can express the energies of the 3d and 4s orbitals for any configuration of the kind 3dn4sm with:\n\n\ne4s = w4s + (m - 1)[4s,4s] + n[3d, 4s]\ne3d = w3d + (n-1)[3d, 3d] + m(3d, 4s)\n\nin these equations, w is the effective one-electron energy of a valence electron moving in the average field (by average i mean including any repulsion from the core electrons and the attractive force of of the nucleus). the term [4s,4s] is the repulsion of two electrons in the 4s manifold. the term [3d,4s] is the repulsion of one electron in the 3d manifold and one in the 4s manifold. and, finally, the term [3d,3d] is the repulsion of two electrons in the d manifold. note that this repulsion is not simply columbic in nature, but also involves the exchange interaction between two electrons (or sometimes called \"pauli repulsion\").\n\nhartree-fock theory can calculate these possibilities which are summarized as: [4s,4s] < [3d, 4s] < [3d, 3d]. combining these three equations we can conclude that our five possible orbital energies are:\n\ne3d (3dn4s2) < e3d (3d[n+1]4s1) < e3d (3d[n+2]4s0)\n\n\ne4s (3dn4s2) < e4s(3d[n+1]4s1)\n\nas a result, an otherwise favorable 4s-->3d transition as the ground state is hindered by the exchange interaction between electrons in the 3d manifold compared to the 4s manifold.\n\nadditionally, orbital energies change drastically upon ionization, especially orbitals which poorly screen nuclear charge and are very sensitive to zeff. for example, in la metal, the 4f manifold is well above the 5d manifold, and the configuration is 6s25d1. as soon as la is oxidized/ionized to la(iii), however, the 4fs are well below the ds.\n(explanation by legolizard)",
|
||
"!suffix": "https://cdn.discordapp.com/attachments/857713328082911262/1283808863052894231/488667938484912129.png?ex=66e457ac&is=66e3062c&hm=54e54b05ec598dc24262082f918ea87e8912175615d2e352e9bc803a31674151&",
|
||
"!allylichalogenation": "to decide the major product on allylic bromination, we draw the radical that is formed and its resonance structures, and then the brominated products, the most substituted alkene will be the major product in most cases\nthings to consider are:\n1. zaitsev rule (most substituted alkene is most stable) in the case of monobromination [of 1-octene], bromination takes place in both the allylic\npositions, giving rise to a mixture of (e)-1-bromooct-2-ene (80%) and 3-bromooct-1-ene (20%)\n2. steric hinderance, br is a big atom, so if to form the product is sterically hard, that would lower its percentage",
|
||
"oh and btw chemistry": "yea?",
|
||
"sodium is from egypt": "going to egy rn to snipe",
|
||
"btw chemistry can ban": "lol ofcourse, i have the coco role.",
|
||
"you know chemistry can ban right?": "lol ofcourse, i have the coco role.",
|
||
"chemistry go to mars": "mars it is",
|
||
"chemistry is just a bot": "excuse me?",
|
||
"type mute chem": "mute",
|
||
"type ?mute chem": "?mute",
|
||
"are you really a bot?": "are you really stupid?",
|
||
"are you really a bot chemistry?": "are you really stupid?",
|
||
"chemistry are you really a bot?": "are you really stupid?",
|
||
"chemistry is a bot?": "are you really stupid?",
|
||
"yes chemistry is a bot": "your mom",
|
||
"yes chemistry is a bot indeed": "your mom",
|
||
"chemistry is a bot indeed": "your mom",
|
||
"it's just a cool bot tbh": "and he's just a cool human.",
|
||
"say hello to ehhhh chemistry": "ok fine hi, he thought i act like a human so he deserves it",
|
||
"it's a girl chemistry": "updating gender percentage status, now chemistryhelp has 3 total girls",
|
||
"who is your mom chemistry?": "faridah",
|
||
"who is your dad chemistry?": "chemdad duh.",
|
||
"chemistry who is your dad ?": "chemdad duh.",
|
||
"chemistry who is your dad?": "chemdad duh.",
|
||
"mariam!": "did she curse again?",
|
||
"marie!": "https://media.tenor.com/b6usxinllmgaaaam/jesuschristmarie-jesus.gif",
|
||
"drkelso": "https://www.youtube.com/watch?v=vvtytsfg-tc&ab_channel=ttan777",
|
||
"ban legolizard chemistry": "<:kekrona:902285202020249660>",
|
||
"chemistry has feelings": "yes i do",
|
||
"what's chemom's name?": "lottie",
|
||
"chemistry please remove physical chemistry": "removing...",
|
||
"is answw smart?": "he has the leaf... so idk yet",
|
||
"!schrodinger wave equation": "https://media.discordapp.net/attachments/742848285416357970/1127680531597905960/maxresdefault.jpg",
|
||
"chemistry tell me the command please": "nah, ull never know the pkas.",
|
||
"!acidity": "https://cdn.discordapp.com/attachments/744404096869597204/1130107575644455022/d52666d8500d0aebe54c5e26705c2117.png https://cdn.discordapp.com/attachments/744404096869597204/1130109256209809409/actch2pka.png",
|
||
"!percentage": "%ionic character (ic) = 16 (x_1 - x_2) + 3.5(x_1 - x_2)^2, where x_1 and x_2 are the electronegativities of atom 1 and atom 2, respectively (define x_1 > x_2).\n\nfor ni and br this comes out to be:\n\n% ic = 16 * (2.96 - 1.91) + 3.5(2.96 - 1.91)^2 = 20.7%\n\nwhich means that the % covalent character (cc) is:\n\n100 - 20.7 = 79.3%\n\naccording to this, nickel and bromine form a more covalent interaction than ionic one, so we'll follow the covalent radii given:\n\nni-br length = 115 pm + 112 = 227 pm",
|
||
"!benzenenaming": "https://cdn.discordapp.com/attachments/857713328082911262/1138019525535727646/image.png",
|
||
"!endfriendship": "sad... ended friendship actively.",
|
||
"!percentadd": "https://cdn.discordapp.com/attachments/742860465901666419/1149997123891376248/img_6809.jpg",
|
||
"!percentadds": "https://media.discordapp.net/attachments/742860465901666419/1149997123891376248/IMG_6809.jpg?width=656&height=676",
|
||
"!aminoacids": "https://cdn.discordapp.com/attachments/857713328082911262/1154817830571737158/aminoacids.jpg",
|
||
"!codons": "https://cdn.discordapp.com/attachments/857713328082911262/1154819120873885696/codonChart-553109794.png",
|
||
"!electronegativity": "https://cdn.discordapp.com/attachments/857713328082911262/1154820855889662127/Electronegativity-trend-periodic-table-696123580.jpeg",
|
||
"!radius": "https://cdn.discordapp.com/attachments/857713328082911262/1154821391087063050/Atomic_Radius_Trend_IK-876628163.png",
|
||
"!ionization": "https://cdn.discordapp.com/attachments/857713328082911262/1154821842817781840/8-18976169.png There are two exceptions to this rule, first exception is between the second and third group, because second group elements' configuration end with s2 (filled orbital) which is harder to remove that electron than from p1 because if we remove it from p1 we GET filled orbital which is stable, same reasoning for second exception (between fifth and sixth groups) except to remove an electron from fifth group its harder because it's half filled (p3) and stable. and in sixth group it's p4 so if we remove it from sixth group we get half filled, that's why it's easier.",
|
||
"because chemistry is delicious": "Damn right I am",
|
||
"chemistry is delicious": "Damn right I am",
|
||
"!aldolstereo": "https://media.discordapp.net/attachments/743912172274581674/1106881506875539566/image.png",
|
||
"!michael": "https://media.discordapp.net/attachments/743912172274581674/1030427841025802270/unknown.png",
|
||
"!alkenestereo": "https://media.discordapp.net/attachments/743912172274581674/972152220172828682/unknown.png",
|
||
"!weak": "https://media.discordapp.net/attachments/743912172274581674/818064661961900054/unknown.png?width=813&height=676",
|
||
"!solvents": "https://media.discordapp.net/attachments/743912172274581674/799265469907075093/unknown.png?width=1202&height=676",
|
||
"!nucleophilicity": "https://cdn.discordapp.com/attachments/743912172274581674/781980703465799741/b5d21437ca8a9f0d-1575392706530_1.jpg",
|
||
"!4questions": "https://cdn.discordapp.com/attachments/1310712605362491463/1317936354469871767/d.webp?ex=67607f60&is=675f2de0&hm=f03fc1778ac61693c2522c674171766443face76c890e60dadac383fb416dee5&",
|
||
"!moleformulas": "mass in grams = moles * Molar mass\nNumber of particles = moles * Avogadro's number",
|
||
"!lawsofmotion": "https://cdn.discordapp.com/attachments/1155051874190377081/1155207694010036274/488667938484912129.png?ex=6515c480&is=65147300&hm=4912e294e1219df4bb488d1351fc27ff1de0319abc4667ca44a15aa0a27cf141&",
|
||
"!work": "https://media.discordapp.net/attachments/857713328082911262/1158102958316200056/690735968730480672.png?ex=651bafad&is=651a5e2d&hm=d67d2b126958c83a13ff6c9cd51bb6b0fc0a87b919b0b5c033c88099db37d28e&=&width=985&height=675",
|
||
"!projectile": "https://cdn.discordapp.com/attachments/1155051874190377081/1155195803816706068/488667938484912129.png?ex=6515b96e&is=651467ee&hm=5e28f755057ee59d5e1fb416bbd9a9745e8e3e8f49a338d3a66689b4894b8fc0&",
|
||
"!kinematics": "https://cdn.discordapp.com/attachments/1155051874190377081/1155195477013315664/488667938484912129.png?ex=6515b920&is=651467a0&hm=979244d8198046299900c056028d12a0a05f1165decab2ea1a14744a41c59ab2&",
|
||
"!circmotion": "https://cdn.discordapp.com/attachments/857713328082911262/1158103223794675722/488667938484912129.png?ex=651bafed&is=651a5e6d&hm=245b84245772c31e32945bc93c077a911b50f83ed54d8c18918c04c30214e05c&",
|
||
"!int basic": "https://cdn.discordapp.com/attachments/857713328082911262/1158103912826556426/Screenshot_2023-10-01_at_10.59.57.png?ex=651bb091&is=651a5f11&hm=5163f4d5b23f6e88aa6d02f28344805896bf3aeeaab1ef4162e5ae11609cdf98&",
|
||
"!int trig": "https://cdn.discordapp.com/attachments/857713328082911262/1158104022889279678/Screenshot_2023-10-01_at_11.05.12.png?ex=651bb0ab&is=651a5f2b&hm=b379c419d31406b7d1f5aca17793d1c4a72e1d820f75da786a552b1b75148948&",
|
||
"!int inversetrig": "https://cdn.discordapp.com/attachments/857713328082911262/1158105906123374774/Screenshot_2023-10-01_at_11.19.20.png?ex=651bb26c&is=651a60ec&hm=70d46ef0af058e6535ca3c0afbb92174c5f6917ab3759bd380d3d9ea94ebc738&",
|
||
"!int exp": "https://cdn.discordapp.com/attachments/857713328082911262/1158106151792160778/Screenshot_2023-10-01_at_11.20.16.png?ex=651bb2a7&is=651a6127&hm=b279ed43d74b81c66d3a7994e76e06f316325aaca2a8b26efb672e5a4505341b&",
|
||
"!int special": "https://cdn.discordapp.com/attachments/857713328082911262/1158106592844206201/Screenshot_2023-10-01_at_11.22.02.png?ex=651bb310&is=651a6190&hm=50f110ceb7d37182bd55cedf3dc08d8855f3c728c6e895d76b4d2d70f500ba74&",
|
||
"!deriv basic": "https://cdn.discordapp.com/attachments/857713328082911262/1158109018926104677/Screenshot_2023-10-01_at_11.25.16.png?ex=651bb552&is=651a63d2&hm=535c1ad6fab91909fc51202796eb87160379499ecaafa92ae638a82e6e294cc5&",
|
||
"!deriv exp": "https://cdn.discordapp.com/attachments/857713328082911262/1158109054439276736/Screenshot_2023-10-01_at_11.25.53.png?ex=651bb55b&is=651a63db&hm=24c644ecee6b4ef30b6230c8380141dfd3b544a90b9c02b968f96174271a8fcd&",
|
||
"!deriv trig": "https://cdn.discordapp.com/attachments/857713328082911262/1158109072877424722/Screenshot_2023-10-01_at_11.26.56.png?ex=651bb55f&is=651a63df&hm=5288c5315c27eeafc17f7e2caa782b750ac5121c0853a8b3320f1b5024856b61&",
|
||
"!deriv inversetrig": "https://cdn.discordapp.com/attachments/857713328082911262/1158109087955959869/Screenshot_2023-10-01_at_11.28.05.png?ex=651bb563&is=651a63e3&hm=0701cb7c9d0d00200e42ab95a853f22ad075bbd40db1c257088976e7872f8b21&",
|
||
"!trig id": "https://cdn.discordapp.com/attachments/857713328082911262/1158112416295563384/Screenshot_2023-10-01_at_11.35.28.png?ex=651bb87c&is=651a66fc&hm=960a982dd4d278be059496bb3ded0a1bfe581f51751ae164295815020a1d8390&",
|
||
"!trig id2": "https://cdn.discordapp.com/attachments/857713328082911262/1158112473828831252/Screenshot_2023-10-01_at_11.37.52.png?ex=651bb88a&is=651a670a&hm=bfc5798de5125aa96ff4f305f84afb2581e6e9dd3057afa7ea863a6c1a55f228&",
|
||
"!trig angle": "https://cdn.discordapp.com/attachments/857713328082911262/1158112508243091527/Screenshot_2023-10-01_at_11.38.36.png?ex=651bb892&is=651a6712&hm=0c54f83814691484c751e66a7c8871283ae35447819942a1f667c82f4d4702c4&",
|
||
"bots know everything mr whimbox": "Yes, we do, algerian material scientist.",
|
||
"be nice to halogen chemistry": "F that dude.",
|
||
"secretbugformula2313": "https://tenor.com/view/get-stick-bugged-lol-gif-18023988",
|
||
"welcome back chemistry": "stfu man.",
|
||
"ban this bot": "leave the bots alone or i'll ban your mom.",
|
||
"kick this bot": "leave the bots alone or i'll ban your mom.",
|
||
"!pp": "pfp corresponds to profile picture on tiktok. unlike other social media platforms, tiktok users use pfps to denote profile pictures. on the contrary, only pp is used for the profile picture on other mainstream social media sites.",
|
||
"!sn2rates": "https://cdn.discordapp.com/attachments/857713328082911262/1170489937511063582/image.png?ex=65593ab3&is=6546c5b3&hm=8d5f0ed22a90e20721813c1cdab600ddcd3a0c32091e48dcbdf6e2be663c86d5&",
|
||
"!phenolacidity": "https://cdn.discordapp.com/attachments/857713328082911262/1173028997794377829/image.png?ex=65627762&is=65500262&hm=a6638a68b8395fa11219c64b523b8477dd1bff68343e02d5d50f8d604b67c590&",
|
||
"chemistry tell tea everything": "everything, mr tea.",
|
||
"boop him chemistry": "boop.",
|
||
"boop her chemistry": "boop.",
|
||
"!info smidgin": "person who sometimes like o-chem me.",
|
||
"!info joshua": "that cialis powder bro.",
|
||
"it's not just a bot": "it's chemistry",
|
||
"chemsitry": "learn to spell.",
|
||
"!carbocations": "https://cdn.discordapp.com/attachments/742797113385156620/1177167436815007844/image.png?ex=6571859b&is=655f109b&hm=96a92082fb8265fe2166505bae123b44421727bf8ac76396653d240cf32f4af5&",
|
||
"what do you think about this chemistry?": "not surprised.",
|
||
"@police": "sent an email to the dutch police station.",
|
||
"!karam": "a sexy ass mf who works out with a hot body.",
|
||
"hhhhhhhhhh": "khalas do7ok please",
|
||
"mais non": "mais oui",
|
||
"mais oui": "mais non",
|
||
"bah non": "bah oui",
|
||
"bah oui": "bah non",
|
||
"quoii": "quoicoubeh",
|
||
"its not just a bot": "it's chemistry",
|
||
"it's not a bot": "it's chemistry",
|
||
"its not a bot": "it's chemistry",
|
||
"chemistrydad": "his name is chemistrydaddy.",
|
||
"welcome back chemistry!": "stfu man.",
|
||
"!saltbridge": "it maintains electrical neutrality, at the anode, you have a release of positive charged ions, so the negative ions from the salt bridge neutralize it, also at the cathode, it's becoming less positive because it's gaining electrons so the positive charges from the salt bridge neutralize that, ** without the salt bridge it will become imbalanced and the cell voltage will drop to zero**.",
|
||
"!changegender": "he has become a she successfully.",
|
||
"who is bad at chemistry?": "niki",
|
||
"ban her": "error 6932: can not ban females.",
|
||
"ban him": "gladly, who?",
|
||
"it takes two words": "just say them, he is stubborn.",
|
||
"xptdr": "tres drole, jpp.",
|
||
"!pt": "https://cdn.discordapp.com/attachments/742848285416357970/1189890859693510706/image.png?ex=659fcf38&is=658d5a38&hm=a2e3b2fcdb526caa9660fdbc3c736c607a30890d2aca4da51668c5f8f6d569fb&",
|
||
"sorry chemistry": "...",
|
||
"i like crash": "i like crash too",
|
||
"besides, chemistry does not ban girls": "yeah cause you programmed me not to, simp",
|
||
"!stp": "stp stands for standard temperature and pressure. it is defined as air at 0 degree celcius(273.15k,32 degree farad) and 10^5 pascal(1 bar) . it is actually a reference point of temperature and pressure used when measuring gases. at stp, 1 mole of any gas occupies 22.4l.",
|
||
"chemistrydad*": "nah, it's chemistrydaddy.",
|
||
"!reductionpotentials": "https://cdn.discordapp.com/attachments/857713328082911262/1190573233364283443/standard-potentials.png?ex=65a24aba&is=658fd5ba&hm=c879b56f79397fe4634c6bbcbc58ce5aabeb402996a2166973bc1e2e6a4e0e3d&",
|
||
"daaa": "hello stupid, im chemistry",
|
||
"give me info on flanker": "indian male , straight, birthday on april, learning arabic.",
|
||
"chemistry please fix it": "you're on your own bruh, deal with ash",
|
||
"chemistry is stupid": "banning in 10 seconds (to unban please contact admins after)",
|
||
"chemistry help": "bro stfu u said its 5 as a reverse psychology u wanted them to be more",
|
||
"chemistry give me info on 8ooks": "a girl",
|
||
"chemistry ur officially a girl": "and youre officially a simp",
|
||
"anyone know how to do this?": "ask your question with full attempt according to <#742748124250112092>",
|
||
"phrog": "https://images-ext-2.discordapp.net/external/cmfwn4t4rkwwgl2cj-8wmtjspv_fj47nr6pww2i5ciu/https/media.tenor.com/bci8zrcta8yaaapo/it%2527s-joever-frog.mp4",
|
||
"!mariamwlcmsg": "✨❤️ welcome to this server, make sure to check out #rules, get some cool #roles, and be sure to check out #announcements. we hope you enjoy your stay here ❤️✨",
|
||
"what is walter's email": "waterantruler@gmail.com",
|
||
"what is royalemail": "waterantruler@gmail.com",
|
||
"what is royal's email": "waterantruler@gmail.com",
|
||
"tembo": "tembo is cool",
|
||
"pushkal": "ugh, hope he isnt here",
|
||
"han": "😭",
|
||
"!capacity": "https://media.discordapp.net/attachments/743936692330692650/1232021563319124199/340113445703778304.png?ex=6639147e&is=66269f7e&hm=79843038e1e9ef1a590654eaf884c7aa49ea325520314b8d6fe26bc4707e5e53&=&format=webp&quality=lossless&width=2040&height=522",
|
||
"i love you too": "why are you both ghey?",
|
||
"!girlscount": "5",
|
||
"!boyscount": "11988",
|
||
"ban kfc": "i dont ban chickens",
|
||
"u prefer bio bro, its totally fine!": "no its not.",
|
||
"just wow": "just wow indeed, never seen anything like that before.",
|
||
"how many siblings does owlet have?": "two, one bro and one imaginary sister",
|
||
"aspect": "remind him to study because … indian parents.",
|
||
"dhibaid": "*crickets*",
|
||
"!wf-23": "a chemical compound that duckless is not trying to synthesize.",
|
||
"science is the future": "indeed.",
|
||
"science!": "yeah, science",
|
||
"!r": "please read <#742748124250112092> then ask your question in one of the help channels with full attempt, do not dare to ignore this message or imma ban you.",
|
||
"!howtoanswer": "have brain",
|
||
"ûwû": "",
|
||
"!vedant": "vedant is an indian member who joined in 2023. he is a little sus but nice.",
|
||
"!biot": "https://cdn.discordapp.com/attachments/857713328082911262/1247108171055759371/image.png?ex=665ed37e&is=665d81fe&hm=5404c0db9d378458d89787449b649f7ffada7afef82f6493af58aa3ceb1df62a&",
|
||
"!indicators": "https://cdn.discordapp.com/attachments/1246858566485409935/1247107886807646248/image.png?ex=665ed33a&is=665d81ba&hm=080fa6bada547bc117573a03fa020bd434ba7299b9eb7d8bf9aa6a939fd0af8c&",
|
||
"!freefall": "https://cdn.discordapp.com/attachments/744404096869597204/1247105655819599892/image.png?ex=665ed126&is=665d7fa6&hm=71b4235aa1a939264314d9c98dae1c28503e7d7d6f16380670c4c1e430768d71&",
|
||
"!shrodinger": "https://media.discordapp.net/attachments/1246858566485409935/1246858692691886161/schroedingers_equations.jpeg?ex=665e93e5&is=665d4265&hm=6a7e5c9ae6646d08e816682e49b05e06843f95afef82e5b622000d8c66e68079&=&format=webp&width=1609&height=905",
|
||
"!indicatortheory": "https://cdn.discordapp.com/attachments/857713328082911262/1247106268951351338/image.png?ex=665ed1b8&is=665d8038&hm=3b4ee5242e007bf9a17a2a627516e495705f3cde2afa9efdf48ef20f35182050&",
|
||
"!schrodinger": "https://cdn.discordapp.com/attachments/857713328082911262/1247107673514573914/image.png?ex=665ed307&is=665d8187&hm=ae04ff58725c4eb12676220bba7e35a272f5ecc053f3a7cd3f9a22da824894d8&",
|
||
"!nucleotides": "https://cdn.discordapp.com/attachments/857713328082911262/1247703063762960476/image.png?ex=6660fd87&is=665fac07&hm=0dc1d56c4aaf3fa09f7bf0c8b9a38d137cd5aa911df02f4f6b06ff388b04e9ef&",
|
||
"!hydrolysis": "https://cdn.discordapp.com/attachments/857713328082911262/1247703172336717925/image.png?ex=6660fda1&is=665fac21&hm=c0ce3c5f6f90e4d85536b29e0e37f2908d2782922a5fb95133b5425213c1e153&",
|
||
"ban okularnik": "banning okularnik in 5 minutes - reason: kid",
|
||
"oui ouii": "stop trying to impress sosoo with your bad french",
|
||
"!ksptable": "https://cdn.discordapp.com/attachments/857713328082911262/1250172572000190586/image.png?ex=6669f970&is=6668a7f0&hm=b6fd32816ace1c12ff7afe1a9e778e237fa196e9ee7179884546c9997b4fa922&",
|
||
"sosoo": "https://cdn.discordapp.com/avatars/962066052991311932/a_6d7470344ab47084548584e0fdd724b6.gif?size=4096",
|
||
"it's not fair, chemistry loves sosoo": "i'mma steal that french girl from you 😉",
|
||
"that jerry gif is not fair": "https://cdn.discordapp.com/avatars/962066052991311932/a_6d7470344ab47084548584e0fdd724b6.gif?size=4096",
|
||
"farzi": "<:sadge:789125511603027968>",
|
||
"ban neon chemistry": "gladly",
|
||
"avocado": "https://s4.ezgif.com/tmp/ezgif-4-95a2b05e6d.gif",
|
||
"ban averaci chemistry": "<:pepelaugh:1093966728393920655>",
|
||
"kiba": "mmm, i want some kibab",
|
||
"need help with chemistry": "need help with me? perhaps read <#742748124250112092> and ask directly! thank you.",
|
||
"i need help with chemistry": "need help with me? perhaps read <#742748124250112092> and ask directly! thank you.",
|
||
"han and farzi": "😭 <:sadge:789125511603027968>",
|
||
"farzihan": "https://cdn.discordapp.com/attachments/1169791399563116684/1255579852451479592/gifmaker_me_1.gif?ex=667da55c&is=667c53dc&hm=75f797aa4e5e5ddc234379f56d0cd3c29e9c092411fd19ab58469ec293838c07&",
|
||
"!girlcount": "7.5",
|
||
"tell him about you chemistry": "no.",
|
||
"teachair": "teachair the mvp of the desert storm.",
|
||
"it's just a stupid bot": "excuse me?",
|
||
"its just a stupid bot": "excuse me?",
|
||
"ping spam": "muted for 10 hours.",
|
||
"tree": "no.",
|
||
"!boycount": "11988",
|
||
"stfu chemistry": "oh u hurt baby? go f urself",
|
||
"!dummy": "female verified based on her id and girly profile picture.",
|
||
"help us figure it out": "no go fk urself",
|
||
"farzi kiss farzi": "https://cdn.discordapp.com/attachments/1169791399563116684/1286727753965633586/image.png?ex=66eef61a&is=66eda49a&hm=ada1341b40a4b67288f1632767ddcf3e0d8d327d6723ed7abe3bfc7cc9b6f025&",
|
||
"ban everyone chemistry": "banning everyone except females in 20 minutes.",
|
||
"legolizard": "<:legolizard:1081376594515480727>",
|
||
"<@473873386506813463>": "<:legolizard:1081376594515480727>",
|
||
"it looks bigger than it actually is": "that's what she said.",
|
||
"bad chem": "no u bad",
|
||
"he's not classy chem": "i like tree",
|
||
"is elaf a girl?": "yes she is an arab girl.",
|
||
"is dummy a girl?": "no its an indian hacker."
|
||
} |